Well, without a Phasechange setup (Prometeia, Vapochill, etc), you can use peltiers. However, uder load, it's pretty hard to get below 0. You can also use dry ice to get below zero. The water is mixed with antifreeze (about the same that you use in the cars radiator) and therefore will be better protected against ice in the loop.
Depending on HOW cold things will be, you probably would use about 75% water, 15% antifreeze and 10% anti-corrotion. Those numbers can vary a lot though.
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