XBMC vs Boxee video play back

which is better?
currently I just use mpc with the k-lite codec pack, but debating setting up the soon-to-be AMD APU HTPC I'm building.
also, can you boot the PC directly into either of these programs?
currently I just use mpc with the k-lite codec pack, but debating setting up the soon-to-be AMD APU HTPC I'm building.
also, can you boot the PC directly into either of these programs?
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and how "good" is that with the AMD E-350 APU?
Either one is good though.
that would be great. 95% of my library is 1080p .mkv
location of said startup folder?
also, I feel I SHOULD have known that